13 Aug 14 Aug 15 Aug 16 Aug 17 Aug 18 Aug 19 Aug 20 Aug 21 Aug
| Starting at 11:00 | ||
| Elena Rybakina KAZ | vs | Mayar Sherif EGY |
| Followed by | ||
| Amanda Anisimova USA | vs | Daria Kasatkina _ |
| Followed by | ||
| Stan Wawrinka SUI | vs | Andy Murray GBR |
| Not before 19:00 | ||
| Matteo Berrettini ITA | vs | Frances Tiafoe USA |
| Not before 20:30 | ||
| Sloane Stephens USA | vs | Alizé Cornet FRA |
| Starting at 11:00 | ||
| Alex Molcan SVK | vs | Diego Schwartzman ARG |
| Followed by | ||
| Benjamin Bonzi FRA | vs | John Isner USA |
| Not before 15:00 | ||
| Jil Teichmann SUI | vs | Petra Kvitova CZE |
| Not before 19:00 | ||
| Kaia Kanepi EST | vs | Victoria Azarenka _ |
| Followed by | ||
| Denis Shapovalov CAN | vs | Grigor Dimitrov BUL |
| Starting at 11:00 | ||
| Roberto Bautista Agut ESP | vs | Francisco Cerundolo ARG |
| Followed by | ||
| Holger Vitus Nodskov Rune DEN | vs | Cameron Norrie GBR |
| Followed by | ||
| Leylah Fernandez CAN | vs | Ekaterina Alexandrova _ |
| Followed by | ||
| Karen Khachanov _ | vs | Sebastian Korda USA |
| Followed by | ||
| Taylor Townsend USA | vs | Ajla Tomljanovic AUS |
| Starting at 11:00 | ||
| Aslan Karatsev _ | vs | Brandon Nakashima USA |
| Followed by | ||
| Emil Ruusuvuori FIN | vs | Jeffrey John Wolf USA |
| Followed by | ||
| Catherine McNally USA | vs | Aliaksandra Sasnovich _ |
| Followed by | ||
| Tereza Martincova CZE | vs | Nuria Parrizas Diaz ESP |
| Not before 17:00 | ||
| Caroline Garcia FRA | vs | Petra Martic CRO |
| Starting at 11:00 | ||
| Barbora Krejcikova CZE | vs | Veronika Kudermetova _ |
| Not before 12:30 | ||
| Sara Sorribes Tormo ESP | vs | Alison Riske-Amritraj USA |
| Not before 14:00 | ||
| Marin Cilic CRO | vs | Jaume Munar ESP |
| Followed by | ||
| Marcos Giron USA | vs | David Goffin BEL |
| Starting at 11:00 | ||
| Eri Hozumi JPN Makoto Ninomiya JPN |
vs | Irina-Camelia Begu ROU Martina Trevisan ITA |
| Followed by | ||
| Yifan Xu CHN Zhaoxuan Yang CHN |
vs | Natela Dzalamidze GEO Monica Niculescu ROU |
| Followed by | ||
| Desirae Krawczyk USA Demi Schuurs NED |
vs | Aleksandra Krunic SRB Magda Linette POL |
| Not before 16:15 | ||
| Kirsten Flipkens BEL Sara Sorribes Tormo ESP |
vs | Lyudmyla Kichenok UKR Jelena Ostapenko LAT |
| Followed by | ||
| Marie Bouzkova CZE Laura Siegemund GER |
vs | Alicja Rosolska POL Erin Routliffe NZL |
| Starting at 13:00 | ||
| Jamie Murray GBR Bruno Soares BRA |
vs | Juan Sebastian Cabal COL Robert Farah COL |
| Not before 14:30 | ||
| Thanasi Kokkinakis AUS Nick Kyrgios AUS |
vs | Simone Bolelli ITA Fabio Fognini ITA |
| Not before 16:00 | ||
| Alex de Minaur AUS Cameron Norrie GBR |
vs | Ivan Dodig CRO Austin Krajicek USA |